Raman spectroscopy has been used for the identification of both common and uncommon minerals in melt inclusions in Group-I kimberlites from Siberia, Canada, SW Greenland and South Africa. The melt inclusions all contained high abundances of alkali-Ca carbonates, with varying proportions of cations, and Na–Ca–Ba sulphates. In accordance with its dry mineralogy, no hydrated carbonates or sulphates were detected in melt inclusions from the Udachnaya-East kimberlite. In contrast, the melt inclusions in kimberlites from Canada, South Africa and SW Greenland were found to contain bassanite, pirssonite, and hydromagnesite suggesting that greater amounts of water were present in their residual magmas. This suggests that enrichment in alkali carbonates and sulphates is widespread across a range of Group-I kimberlites and implies that they commonly have an alkali-, and sulphur-rich residual liquid.
History
Publication title
Spectrochimica Acta. Part A: Molecular and Biomolecular Spectroscopy
Volume
80
Pagination
82-87
ISSN
1386-1425
Department/School
School of Natural Sciences
Publisher
Pergamon-Elsevier Science Ltd
Place of publication
The Boulevard, Langford Lane, Kidlington, Oxford, England, Ox5 1Gb