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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates

journal contribution
posted on 2023-05-19, 04:42 authored by Noor, A, Li, J, Khairallah, GN, Li, Z, Ghari, H, Allan CantyAllan Canty, Alireza AriafardAlireza Ariafard, Donnelly, PS, O'Hair, RAJ
A new palladium mediated “one pot” synthesis of thioamides from aromatic carboxylic acids (ArCO2H + RNCS → ArC(S)NHR + CO2) was discovered by gas-phase experiments and theoretical studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives.

History

Publication title

Chemical Communications

Volume

53

Issue

27

Pagination

3854-3857

ISSN

1359-7345

Department/School

School of Natural Sciences

Publisher

Royal Soc Chemistry

Place of publication

Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0Wf

Rights statement

© The Royal Society of Chemistry 2017

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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    University Of Tasmania

    Categories

    Keywords

    metal mediated synthesisthioamide synthesisorganopalladium

    Licence

    In Copyright

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