Asymmetric Cyclopropanation of Olefins with an in situ Generated
journal contribution
posted on 2023-05-17, 00:21 authored by Muller, P, Ghanem, AA procedure for the in situ generation of the phenyliodonium ylide (2) derived from Meldrum's acid (1) and its Rh(II)-catalyzed decomposition to afford an intermediate metallocarbene is described. In the presence of olefins, cyclopropanes are formed with yields and enantioselectivity comparable to that resulting from cyclopropanation with the isolated ylide 2.
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Publication title
SynlettVolume
2003Issue
12Pagination
1830-1833ISSN
1437-2096Department/School
School of Natural SciencesPublisher
Thieme-VerlagPlace of publication
GermanyRights statement
© Georg Thieme Verlag 2003Socio-economic Objectives
Expanding knowledge in the chemical sciencesRepository Status
- Restricted
