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Chiral dirhodium catalysts: A new era for asymmetric catalysis

journal contribution
posted on 2023-05-17, 12:27 authored by El-Deftar, M, Adly, FG, Michael GardinerMichael Gardiner, Ghanem, A
The catalysis by dirhodium paddlewheel complexes has been an area of immense interest and extensive study over the past three decades - not only because most of the catalysts are highly stable to heat, moisture and ambient atmosphere but also for the asymmetric induction in the ylide generation. In this review, we attempt to provide an overview on the general preparation method for most homogeneous chiral dirhodium(II) catalysts that have appeared to date and their recent applications in asymmetric catalysis with iodonium ylides as carbenoid precursors.

History

Publication title

Current Organic Chemistry

Volume

16

Issue

15

Pagination

1808-1836

ISSN

1385-2728

Department/School

School of Natural Sciences

Publisher

Bentham Science

Place of publication

Hilversum, Netherlands

Rights statement

Copyright 2012 Bentham Science Publishers.

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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