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Chloro(phenyl)(1H-pyrazole-kappa N-2)-(triphenylphosphine-kappa P)palladium(II)

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posted on 2023-05-16, 15:37 authored by Allan CantyAllan Canty, Skelton, BW, White, AH
In the title compound, [Pd(C6H5)Cl(C 3H4N2)(P(C6H5) 3}], the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a square-planar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra- and intermolecular component.

History

Publication title

Acta Crystallographica Section C - Crystal Structure Communications

Volume

60

Issue

8

Pagination

m405-m406

ISSN

0108-2701

Department/School

School of Natural Sciences

Publisher

Blackwell Munksgaard

Place of publication

Copenhagen

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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