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Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes
journal contributionposted on 2023-05-26, 16:10 authored by Byers, PK, Canty, AJ, Jin, H, Kruis, D, Markies, BA, Boersma, J, van Koten, G, Hill, GS, Irwin, MJ, Rendina, LM, Puddephatt, RJ
Syntheses of organopalladium(II) reagents containing N,N,N',N'-tetramethylethylenediamine (tmeda), pyridazine, dimethylsulfide, 2,2'-bipyridine (bpy), triphenylphosphine and bis(1,1'-diphenylphosphino)ferrocene (dppf) are described, together with trans-dichlorobis(dimethylsulfide)palladium(II) and trans-dibromobis(dimethylsulfide)palladium(II). Syntheses are described for dimethyl(pyridazine)palladium(II), monomethylpalladium(II) complexes of dimethylsulfide, [PdMe(SMe2)(mu-X)]2 (X = Cl, Br, I), PdMe2(tmeda) and PdXMe(tmeda) (X = Cl, Br, I), PdMe2(dppf) and PdXMe(dppf) (X = Cl, Br, I), cis-PdMe2(PPh3)2 and trans-PdClMe(PPh3)2 (X = Cl, Br, I), and trans-PdXMe(bpy) (X = Cl, Br, I).
Publication titleInorganic Syntheses
Department/SchoolSchool of Computing
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