Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex
journal contribution
posted on 2023-05-16, 13:31authored byNielsen, DJ, Magill, AM, Brian YatesBrian Yates, Cavell, KJ, Skelton, BW, White, AH
Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.
History
Publication title
Chemical Communications
Issue
21
Pagination
2500-2501
ISSN
1359-7345
Department/School
School of Natural Sciences
Publisher
The Royal Society of Chemistry
Place of publication
Cambridge, England, UK
Repository Status
Restricted
Socio-economic Objectives
Organic industrial chemicals (excl. resins, rubber and plastics)