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Facile synthesis and coupling of functionalized isomeric biquinolines

journal contribution
posted on 2023-05-17, 12:28 authored by Tomar, M, Lucas, NT, Michael GardinerMichael Gardiner, Mullen, K, Jacob, J
A simple route toward functionalized biquinolines, namely 8,5'-dibromo-5,8'-biquinoline 1 and 5,5'-dibromo-8,8'-biquinoline 2, was developed using Skraup syntheses. Both the dibromo compounds undergo facile Suzuki coupling to afford fluorene-coupled products 3 and 4, respectively, an important transformation in designing conjugated materials based on these cores. X-ray structural analyses of 1 and 4 provide insight into the mode of packing within materials containing these units.

History

Publication title

Tetrahedron Letters

Volume

53

Pagination

285-288

ISSN

0040-4039

Department/School

School of Natural Sciences

Publisher

Pergamon-Elsevier Science Ltd

Place of publication

Oxford

Rights statement

Copyright 2011 Elsevier Ltd

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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