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Micropatterned surfaces for atmospheric water condensation via controlled radical polymerization and thin film dewetting

journal contribution
posted on 2023-05-18, 13:16 authored by Wong, I, Teo, GH, Neto, C, Stuart ThickettStuart Thickett
Inspired by an example found in nature, the design of patterned surfaces with chemical and topographical contrast for the collection of water from the atmosphere has been of intense interest in recent years. Herein we report the synthesis of such materials via a combination of macromolecular design and polymer thin film dewetting to yield surfaces consisting of raised hydrophilic bumps on a hydrophobic background. RAFT polymerization was used to synthesize poly(2-hydroxypropyl methacrylate) (PHPMA) of targeted molecular weight and low dispersity; spin-coating of PHPMA onto polystyrene films produced stable polymer bilayers under appropriate conditions. Thermal annealing of these bilayers above the glass transition temperature of the PHPMA layer led to complete dewetting of the top layer and the formation of isolated PHPMA domains atop the PS film. Due to the vastly different rates of water nucleation on the two phases, preferential dropwise nucleation of water occurred on the PHPMA domains, as demonstrated by optical microscopy. The simplicity of the preparation method and ability to target polymers of specific molecular weight demonstrate the value of these materials with respect to large-scale water collection devices or other materials science applications where patterning is required.


Publication title

ACS Applied Materials and Interfaces










School of Natural Sciences


American Chemical Society

Place of publication

United States of America

Rights statement

Copyright 2015 American Chemical Society

Repository Status

  • Restricted

Socio-economic Objectives

Terrestrial systems and management not elsewhere classified

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