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Nanoporous polymers from cross-linked polymer precursors via tert-butyl group deprotection and their carbon dioxide capture properties
journal contribution
posted on 2023-05-19, 20:34 authored by Huang, J, Zhou, X, Lamprou, A, Fernando Maya AlejandroFernando Maya Alejandro, Svec, F, Turner, SRA two-step synthetic strategy has been developed to achieve functionalized nanoporous polymers via the deprotection of the cross-linked polymer precursors containing tert-butyl carboxylate-functionalized stilbene or styrene and N-phenylmaleimide alternating sequences. Three different deprotection methods to generate nanoporosity were examined in this work. The resulting nanoporous polymers showed a significant increase in BET surface area. The effects of cross-linking density and the stiffness of the alternating sequences on the nanoporosity of these polymers were studied. The resulting nanoporous polymers were also investigated as potential CO2 sorbents.
History
Publication title
Chemistry of MaterialsVolume
27Issue
21Pagination
7388-7394ISSN
0897-4756Department/School
School of Natural SciencesPublisher
Amer Chemical SocPlace of publication
1155 16Th St, Nw, Washington, USA, Dc, 20036Rights statement
Copyright 2015 American Chemical SocietyRepository Status
- Restricted