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Properties of microdispersed sintered nanodiamonds as a stationary phase for normal phase high-performance liquid chromatography
journal contribution
posted on 2023-05-17, 00:53 authored by Nesterenko, PN, Fedyanina, ONThe chromatographic properties of microdispersed sintered nanodiamonds (MSND) are studied under conditions of normal-phase HPLC. The retention characteristics of 30 substances representing four classes of aromatic compounds including monoalkylbenzenes, poly- methylbenzenes, di-n-alkyl phthalates and polyaromatic hydrocarbons in n-alkane mobile phases have been measured. The selectivity of MSND was compared with literature data for other common adsorbents including silica gel, alumina and porous graphitic carbon (PGC). MSND shows the distinctive adsorption properties especially in a stronger retention of aromatic hydrocarbons and in the better selectivity of the separation of geometric isomers. The significant improvement in separation efficiency up to 45300 theoretical plates per meter, was achieved for the first time for the columns packed with diamond related materials (DRM).
Funding
University of Tasmania
History
Publication title
The Journal of Chromatography AVolume
1217Issue
4Pagination
498-505ISSN
0021-9673Department/School
School of Natural SciencesPublisher
Elsevier Science BvPlace of publication
Po Box 211, Amsterdam, Netherlands, 1000 AeRights statement
The definitive version is available at http://www.sciencedirect.comRepository Status
- Restricted