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Reduction of a chelating bis(NHC) palladium(II) complex to [{mu-bis(NHC)}2Pd2H]+: A terminal hydride in a binuclear palladium(I) species formed under catalytically relevant conditions

journal contribution
posted on 2023-05-17, 03:03 authored by Boyd, PDW, Edwards, AJ, Michael GardinerMichael Gardiner, Curtis HoCurtis Ho, Lemee-Cailleau, MH, McGuinness, DS, Riapanitra, A, Steed, JW, Stringer, DN, Brian YatesBrian Yates
Catalytic processes featuring N-heterocyclic carbene (NHC) ligands have been extensively studied following the isolation of free imidazol-2-ylidenes An important reaction class is the base-assisted palladium-mediated C–C/N coupling, such as the Sonogashira, Buchwald–Hartwig, and Mizoroki–Heck reactions

History

Publication title

Angewandte Chemie International Edition

Volume

49

Issue

36

Pagination

6315-6318

ISSN

1433-7851

Department/School

School of Natural Sciences

Publisher

Wiley-Blackwell

Place of publication

Malden, USA

Rights statement

The definitive published version is available online at: http://onlinelibrary.wiley.com/

Repository Status

  • Restricted

Socio-economic Objectives

Inorganic industrial chemicals

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    University Of Tasmania

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    In Copyright

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