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Reductive disproportionation of carbon dioxide by a Sm(II) complex: Unprecedented f-block element reactivity giving a carbonate complex
journal contributionposted on 2023-05-16, 18:49 authored by Noel DaviesNoel Davies, Frey, A, Michael GardinerMichael Gardiner, Wang, J
A macrocyclic organosamarium(ii) complex has been shown to provide the first example of the reductive disproportionation of carbon dioxide, giving a bimetallic carbonate complex and carbon monoxide in a facile reaction under ambient conditions. Â© The Royal Society of Chemistry 2006.
Publication titleChemical Communications
Department/SchoolSchool of Natural Sciences
PublisherRoyal Society of Chemistry
Place of publicationCambridge