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Structural chemistry of dihalogenopalladium(II) and platinum(II) complexes of heteroleptic N,S- and N,Se- donor ligands based on the 2-organochalcogenomethylpyridine motif

journal contribution
posted on 2023-05-17, 12:17 authored by Jones, RC, Allan CantyAllan Canty, Michael GardinerMichael Gardiner, Tolhurst, V
The structural chemistry of dihalogenopalladium(II) and platinum(II) complexes of 2-organochalcogenomethylpyridine ligands is described. Complexes with a methyl group in the 6-position of the pyridyl ring, 6-MepyCH(2)ER, form dimeric complexes [trans-PdX(2)(mu-6-MepyCH(2)SePh-N,Se)](2) (X = Br (1), I (2)) or mononuclear complexes trans-PdI(2)(6-MepyCH(2)SR-N)(2) (R = Me (5), Ph (6)). Absence of a 6-methyl substituent results in the bidentate configuration observed for PdI(2)(pyCH(2)SePh-N,Se) (3) and PdI(2)(4-MepyCH(2)SMeN, S) (4). Related platinum(II) complexes are mononuclear including PtCl(2)(6-MepyCH(2)SPh-N,S) (8) as an analogue of trimeric [trans-PdCl(2)(mu-6-MepyCH(2)SPh-N,S)](3). Differences between palladium and platinum appear to result from a combination of steric and electronic factors.

History

Publication title

Inorganica Chimica Acta: The International Inorganic Chemistry Journal

Volume

376

Pagination

290-295

ISSN

0020-1693

Department/School

School of Natural Sciences

Publisher

Elsevier Science Sa

Place of publication

Po Box 564, Lausanne, Switzerland, 1001

Rights statement

Copyright 2011 Elsevier B.V.

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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