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Sulfur Isotope Evidence for Magmatic Contributions to Submarine and Subaerial Gold Mineralization: Conical Seamount and Ladolam Gold Deposit, Papua New Guinea

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posted on 2023-05-16, 16:04 authored by John GemmellJohn Gemmell, Sharpe, R, Jonasson, IR, Herzig, P
Conical seamount is a submarine alkali basalt volcano situated 10 km south of Lihir Island in the Tabar-Feni island chain, Papua New Guinea. Polymetallic (Zn-Pb-Ag-Au-As-Sb) veins, pyritic stockwork, and hydrothermally altered rocks discovered on the summit of Conical seamount represent a unique example of submarine gold mineralization with mineralogical, chemical, and textural characteristics common to some subaerial epithermal systems. The giant Ladolam epithermal gold deposit (42 Moz Au) is situated in the crater of an alkali stratovolcano on Lihir Island. Portions of the epithermal mineralization and alteration assemblages at Ladolam are similar to those observed on Conical seamount. Conical seamount has the lightest, hydrothermal (i.e., nondiagenetic) sulfide δ34S values (-17.5 to +6.1‰) measured to date from modern sea-floor hydrothermal systems. A previous model for the Conical seamount hydrothermal system suggested a contribution of magmatic volatiles in the earliest stages of mineralization (stage 1), followed by a combination of sulfur leached from the underlying volcanic rocks and reduced seawater sulfate during the main base and precious metal precipitating event (stage 2). New sulfur isotope data allow a reinterpretation of this model that suggests a greater input of magmatic volatiles, plus boiling, throughout both stage 1 and 2 mineralization. Sulfides from the Ladolam gold deposit have a range of sulfur isotope values (-12.9 to +3.6‰) similar to that of Conical seamount. These sulfur isotope data have previously been interpreted as the result of magmatic volatiles escaping from a crystallizing magma and mixing with dilute meteoric ground water. Anhydrite, associated with the gold mineralization has two populations of δ34S values (8-14 and 20-22‰), which indicate the interaction of magmatic volatiles with seawater that has previously been discounted. The range of sulfide and sulfate δ34S values at Ladolam is reinterpreted to be due to a complex interaction of magmatic hydrothermal fluids, meteoric ground water, and seawater. Native sulfur in thermal areas in Luise caldera and pyrite in offshore hydrothermal vents in Luise harbor have similar δ34S values to the Ladolam epithermal mineralization, indicating that fluids similar to the young Ladolam ore-forming event are still reaching the floor of Luise caldera. Sulfur isotope data from Conical seamount and the Ladolam depo sit suggest that magmatic volatiles have contributed a significant amount of sulfur to both these gold-rich hydrothermal systems. © 2004 by Economic Geology.

History

Publication title

Economic Geology and the Bulletin of the Society of Economic Geologists

Volume

99

Issue

8

Pagination

1711-1725

ISSN

0361-0128

Department/School

School of Natural Sciences

Publisher

Economic Geology Publ Co

Place of publication

Littleton, CO, USA

Repository Status

  • Restricted

Socio-economic Objectives

Precious (noble) metal ore exploration

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