SYNTHESIS OF THE 1ST ORGANOPALLADIUM(IV) CATIONS, INCLUDING THE 1ST X-RAY STUDY OF ISOSTRUCTURAL ORGANOPALLADIUM(IV) AND PLATINUM(IV) COMPLEXES, [FAC-MME3(TRIS(PYRAZOL-1-YL)METHANE-N,N',N'')]I

BYERS, PK; Canty, Allan; SKELTON, BW; WHITE, AH

SYNTHESIS OF THE 1ST ORGANOPALLADIUM(IV) CATIONS, INCLUDING THE 1ST X-RAY STUDY OF ISOSTRUCTURAL ORGANOPALLADIUM(IV) AND PLATINUM(IV) COMPLEXES, [FAC-MME3(TRIS(PYRAZOL-1-YL)METHANE-N,N',N'')]I

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posted on 2025-06-20, 01:55 authored by PK BYERS, Allan CantyAllan Canty, BW SKELTON, AH WHITE

Stable organopalladium(IV) complexes [fac-PdMe3(L)]I (L = tridentate nitrogen donor ligand) are formed on oxidative addition of iodomethane to PdMe2(L); the tris (Pyrazol-1-yl)methane complex is isostructural with the platinum(IV) analogue.<p></p>

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DOI - Is supplement to Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N',N'' }]I

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Chemical Communications

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14

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1093-1095:3

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1359-7345

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Chemistry

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ROYAL SOC CHEMISTRY

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SYNTHESIS OF THE 1ST ORGANOPALLADIUM(IV) CATIONS, INCLUDING THE 1ST X-RAY STUDY OF ISOSTRUCTURAL ORGANOPALLADIUM(IV) AND PLATINUM(IV) COMPLEXES, [FAC-MME3(TRIS(PYRAZOL-1-YL)METHANE-N,N',N'')]I

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