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The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl)
journal contributionposted on 2023-05-25, 22:39 authored by Byers, PK, Canty, AJ, Skelton, BW, White, AH
Oxidative addition of iodomethane to dimethyl(2,2'-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2'-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form methyl(2,2'-bipyridy1)iodopalladium(II).
Publication titleJournal of the Chemical Society, Chemical Communications