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Unsymmetric Tripod Ligands Related To Tris(pyrazol-1-yl)methane
journal contribution
posted on 2023-05-26, 10:57 authored by Byers, PK, Canty, AJ, Honeyman, RT, Gardinier, JR, Reger, DLThe syntheses of tripodal ligands related to tris(pyrazol-1-yl)methane are described. The synthesis of bis(pyrazol-1-yl)methanone, N-methylimidazole-2-carbaldehyde, bis(pyrazol-1-yl)(pyridin-2-yl)methane and bis(pyrazol-1-yl)(N-methylimidazol-2-yl)methane are documented. The synthetic strategy relies on condensation of bis(pyrazol-1-yl)methanone, (pz)2C=O, with aldehydes, R(H)C=O, to give (pz)2(R)CH and carbon dioxide.
History
Publication title
Inorganic SynthesesVolume
34Pagination
30-34ISSN
0073-8077Publication status
- Published
Repository Status
- Restricted