whole_WangJun2003_thesis.pdf (9.83 MB)
Organolanthanide chemistry of modified porphyrinogens
thesisposted on 2023-05-27, 14:55 authored by Wang, Jun
This thesis describes studies into the synthesis, characterisation and reactivity of samarium(II) and (Ill) halide, alkyl and amide complex~s derived from the modified porphyrinogens meso-octaethyl-trans-dioxaporphyrinogen, Et8O2N2H2, and trans-N,N'-dimethyl-meso-octaethylporphyrinogen, Et8NMe2H2. The macrocycles themselves and various Group 1 metal derivatives that are accessed in the preparation of the target lanthanide complexes are also described in relation to their synthesis, characterisation and reactivity.
Rights statementCopyright 2003 the Author - The University is continuing to endeavour to trace the copyright owner(s) and in the meantime this item has been reproduced here in good faith. We would be pleased to hear from the copyright owner(s) Thesis (Ph.D.)--University of Tasmania, 2003. Includes bibliographical references